Ternary materials for lithium ion batteries
Ternary materials for
lithium-ion batteries are lithium
ion battery technology in the
development of a new type of cathode materials for lithium-ion batteries,
because of its comparative advantage, ternary lithium-ion battery materials
showed broad prospects on the application in the market.
Cathode
material for lithium-ion battery from lithium to lithium cobalt oxide,
manganese oxide, ternary material into three types (In addition to the dynamic
type of lithium iron phosphate), So-called ternary materials for lithium-ion
batteries is nickel, cobalt, and manganese salts as raw material, nickel and
cobalt and manganese are three elements (ternary) battery cathode materials
made of mixed in different proportions.
The
advantages of lithium cobalt oxide significantly, but the high price of Cobalt metal,
has the advantages of lithium manganese oxide ratio performance, low cost, high
temperature resistance and poor performance, ternary material for lithium-ion
battery is integrated the advantages of both aimed at the highest ratio of cost
and performance.
Ternary lithium battery materials are divided into two stages,
the first stage is the precursor preparation of ternary materials, including
the synthesis of mixture of nickel, cobalt and manganese ions, and precipitants
of mixed liquid precipitation reactions and aged, washed, filtered, dry second
stage is preparation of ternary lithium-ion battery materials, including
lithium salt and mixing, milling and interning process of precursor.
According
to the three elements in the mixed in varying proportions, at present, the
commercialization of ternary materials for lithium-ion batteries are: (1)(1)LiNi(1/3)Co1/3)Mn(1/3)O2、(2)LiNi(0.4)Co(0.2)Mn(0.4)O2(3)LiNi(0.5)Co(0.2)Mn(0.3)O2.
Among
them, the first is the best, in this ternary materials for lithium-ion
batteries at different temperature and structural changes of magnification
smaller, has better stability, because the replaced part with a
nickel-manganese-cobalt materials, which has a comparative cost advantage, but
LiNi(0.4)Co(0.2)Mn(0.4)O2LiNi(0.5)Co(0.2)Mn(0.3)O2 because of less cobalt
prices cheaper, but the disadvantage is that stability decreases, are also part
of the nickel to trivalent form, poorly controlled more easily absorb water,
also affect the stability of batteries.
Overall,
the comparative advantages of ternary materials for lithium-ion batteries: high
capacity, long cycle life, good safety performance, low price, which comes from
the synergy of the three elements: cobalt caution mixture can be reduced,
stability of layered structure; nickel can improve the capacity of and
manganese can reduce costs and increase security.
Since
the technology is still in development, current ternary materials for
lithium-ion batteries also have two disadvantages: first are the relatively low
platforms, the second is the first low efficiency. However, attracted by the
strong comparative advantage, a growing number of battery suppliers became
interested in ternary lithium-ion battery materials, preparing or had already
begun to ternary materials of lithium battery manufacturer.
Contact:
Person:
Tim.lee
Company:
Dongguan Large Electronics Co., Ltd
Add:
Block A, Gaosheng Technology Zone, Nancheng District, Dongguan City, Guangdong
Province, CN
Tel:
86-769-23182621
Email:
Tim.lee@largepower.cn
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